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| The
Exhibits Hall 2007 |
| Oundle
School, Northants - Thursday 15th March 2007 |
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Back to Main Exhibit Hall Page
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Puzzling
Plastics - stringy substances and giant vortices
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IRC
in Polymer Science and Technology, Dept of Physics and Astronomy,
University of Leeds, LEEDS LS2 9JT
Dr John Embery
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For fifty years,
plastics have successfully concealed their secret life from us.
The processing and use of plastics has leapfrogged ahead of our
understanding of what is happening when the plastic is moulded into
a object; whether that object is Wayne Rooney's shin guard, a Pussycat
Dolls DVD or the casing of the latest mobile phone.
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A polymer
liquid getting really stressed.
Predicted stress patterns for a liquid polymer made of branched
molecules flowing through a constriction - the flow determines
the final properties of the plastic
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the last fifty years, whilst the world's oil has been transformed
into more and more plastic, we have been wrestling to catch up with
the science of plastic molecules. This is a necessity if we are to
develop such things as super-tough plastic pipes, ultra-thin and massively
strong plastic bags or lighter replacements for metal in vehicles
and thus, ultimately use the world's resources more effectively. In
order to decipher the behaviour of plastics we need to analyse and
understand, using mathematical and experimental tools, how polymer
liquids flow when they are in the melt state just prior to being squeezed
and cooled into a new useful shape. |
Stressed polymer
grows fangs!
The flow of molecules in liquid polymers can now be predicted with
accuracy - predicted flow (left) and observed flow (right) through
a channel; the "fangs" are a fingerprint signature of
branched molecules.
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The ultimate
step of this project is the development and hard-testing of molecular
theory and process modelling before it is then applied to more typical
industrial materials. A recent example of this has been to independently
predict and experimentally measure the stress field that a polymer
liquid experiences as it is squeezed in two directions at once.
The close correlation of the two analyses shows that the theory
is becoming more sophisticated in predicting real processing situations.
Enormous strides
have meet made in the last fifty years in attempting to describe
polymer flow with mathematical modelling. Polymeric materials are
greatly affected by the motion of molecules and the heat that derives
from that. Statistical mechanics is concerned with what happens
when things get hot. From the statistical mechanics of gases, physicists
can do statistical mechanics on connected chains - the giant chains
of polymers. General relativity enables physicists to measure curvature
of molecular paths in space and in membranes, the two-dimensional
polymers that underpin so much of biology (cells and cell walls).
And quantum field theory, with its notion of summing over all fluctuating
states, enables physicists to calculate the way polymers move under
thermal fluctuation.
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The Poster
Presentations are judged and prizes totalling
£1500
are to be awarded at Showase Science 2007.
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